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Tank-Mix Compatibility Calculator: W.A.L.E.S.+

Don't waste a UAH 50K+ tank on the wrong mix. Pick up to 4 products — the calculator returns an overall verdict (✅/⚠️/🚫), the W.A.L.E.S.+ mixing order, antagonism for each pair from a matrix of 30 combinations documented in Ukraine, pH warnings, Law 1492-III bee buffers, and the mandatory jar-test protocol.

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Tank-mix composition

Add up to 4 products. The calculator checks every pair for compatibility, builds the W.A.L.E.S.+ mixing order, and flags pH antagonism + bee safety.

1Product 1
Formulation: ECW.A.L.E.S. 4
2Product 2
Formulation: SCW.A.L.E.S. 3
3Product 3
✅ Compatible

No documented conflict across the selected pairs. A jar test is mandatory once you hit 3+ products.

W.A.L.E.S.+ mixing order

Canonical addition order: Wettable → Agitation → Liquid flowables (SC) → Emulsifiable concentrates (EC) → Solubles (SL / AS / adjuvants). Water conditioners (AMS) are the EXCEPTION and go in BEFORE any active ingredient.

  1. W
    Wettable powders / water-dispersible granules
    ADD FIRST. Pre-slurry in cold water if clumping is a risk (WP/WG). Keep bypass agitation on.
  2. L
    Liquid flowables / suspension concentrates
    ADD SECOND. Easily homogenized; pre-dilute before EC chemistry.
    • FluxapyroxadSC
  3. E
    Emulsifiable concentrates / oil-based
    ADD THIRD. Needs water already present for a stable emulsion.
    • ProthioconazoleEC
  4. S
    Solubles / surfactants / adjuvants
    ADD LAST. AMS / water conditioners are the EXCEPTION: load BEFORE any AI in hard water.

Verdict for each pair

  • Prothioconazole+Fluxapyroxad
    T1 winter-wheat work-horse for Septoria + broadleaves. AMS pre-load in hard water.
    Batch 3 §5.2 row 1
    ✅ Compatible

How the calculation works

The calculator builds on six rules from ADAM's pesticide knowledge base. One: W.A.L.E.S.+ is the canonical addition order into the tank — wettable powders first (WP/WG/WDG/SG/SP, pre-slurried in cold water), continuous agitation via bypass flow, liquid flowables second (SC/OD/CS/FS — easy homogenization), emulsifiable concentrates third (EC/EW/UL — need water already present for a stable emulsion), solubles and surfactants last (SL/AS/adjuvants). The physics: water-dispersible solids need hydration time and EC emulsions collapse when added before water. AMS and water conditioners are the EXCEPTION and go in BEFORE any active ingredient in hard water. Two: antagonism for each pair — every C(n,2) pair is looked up among 30 combinations documented in Ukraine. Examples: glyphosate + clethodim (ACCase) is incompatible; copper + Bacillus is incompatible. Missing pairs fall to general rules (glyphosate + HRAC-1, biological + copper/sulphur). Three: no more than 4 products — 60 years of field research shows reliability drops sharply beyond four products. Four: the jar test — before the full tank-fill, combine 10 mL of each product in a 100 mL jar in the W.A.L.E.S.+ order, wait 15 minutes, and abandon the mix if you see separation, flocculation, gel, colour change, heat, or gas. Five: pH antagonism windows (sulfonylureas, glyphosate, copper, pyrethroids, biologicals). Six: Law 1492-III — if any active ingredient is bee-toxic, enforce 5 km aerial / 1 km near settlement / 500 m ground buffers, 48 h pre-notification to beekeepers via ОТГ, prohibited-hours window 09:00–20:00, T ≤ 30°C, wind ≤ 4 m/s.

  1. 1

    Add product 1

    Pick an active ingredient from the catalogue of the 60 most common registered in Ukraine. The calculator auto-fills the primary formulation (EC/SC/WG/SL) and the W.A.L.E.S. position.

  2. 2

    Add products 2–4 (optional)

    Up to 4 products. Beyond that the add button locks — 60 years of spray research shows reliability collapses past four products in a single tank.

  3. 3

    Read the overall verdict

    ✅ Compatible — no conflict; ⚠️ Compatible with caution — partial conflict; 🚫 DO NOT MIX — documented antagonism, split the applications 5–7 days apart.

  4. 4

    Check the W.A.L.E.S.+ order

    Each product lands in its slot (W / L / E / S) with a pre-slurry / pre-dilute / direct-pour note. Load the tank strictly in that order.

  5. 5

    Read pairwise verdicts + pH warnings

    If any pair is partial / incompatible, read the rationale. If any AI carries a pH sensitivity (sulfonylureas, glyphosate, copper) test the tank-water pH (target 5–7 for most AI).

  6. 6

    Run the small-jar test before tank-fill

    Mandatory at 3+ products. In a 100 mL jar, 10 mL of each in the W.A.L.E.S.+ order, shake, 15 minutes. Abort on separation / gel / colour / heat. The calculator is advisory; the jar test is the safety net.

When to use this tool

  • Vet a planned winter-wheat T1 mix (fungicide + insecticide + adjuvant) before a 1,000 ha spray
  • Rule out phytotoxic combinations worth UAH 80K+ on a spring sunflower Phomopsis / Alternaria pass
  • Compare two competing 3-product mixes for the same target pest (thrips, Septoria, wild oat)
  • Quick-check a farmer's spray plan at the dealer counter before placing the input order

Limitations

Only the 60 most common active ingredients registered in Ukraine are covered — regional and niche ones will follow. Pairs only — interactions of three or more products are not modelled; the jar test is the safety net. Bee buffers are the minimum under Law 1492-III — local communities (ОТГ) or oblast administrations can set stricter buffers (check). The product label comes first — the calculator is advisory, not regulatory. Water quality (pH, hardness, chlorine) is modelled indirectly through active-ingredient classes — a full input is planned for a later version. Warning: a bad tank mix on 1,000 ha can cost more than UAH 100K through phytotoxicity, failed control, injector / DPF damage (oil-EC spillage), or bee-kill with legal exposure under Law 1492-III.

Frequently asked questions

What does W.A.L.E.S.+ mean?
W.A.L.E.S. is the canonical order for adding pesticides into a spray tank: Wettable powders (WP / WG / WDG) → Agitation (continuous bypass flow) → Liquid flowables (SC / OD / CS — suspension concentrates) → Emulsifiable concentrates (EC / EW — oil-based chemistry) → Solubles + surfactants (SL / AS / adjuvants). The «+» adds one exception: Ammonium Sulfate (AMS) + water conditioners ALWAYS go first, before any AI, in hard water. The physics: WG / SC need hydration time; EC emulsions collapse if added before water; adjuvants activate the effect and must be last. Wrong order = clumping, pump damage, failed control.
Can I exceed 4 products?
Technically yes, practically no. The 4-product limit rests on 60 years of field research (Purdue, UNL, NAGRO UA): beyond four, reliability collapses — emulsion failure, precipitation, pump wear, sprayer-tip blockage. The calculator disables the 5th slot. If a plan needs 5+ products, split into two applications 5–7 days apart. Exceptions — only pre-registered pre-mixes (e.g. Ampligo = chlorantraniliprole + lambda-cyhalothrin) plus up to two tank-mix partners.
Why does the order matter?
W.A.L.E.S. order solves three physical problems. (1) Wettable porous solids (WG / WP) need hydration time in water — added after EC they clump and block the boom / nozzle (the farmer loses a day to flushing). (2) Emulsifiable concentrates (EC) — oil chemistry; added before water they stay non-homogenized, and the pump feeds an «oil-water-oil» cocktail with uneven concentration across the field. (3) Solubles + adjuvants (SL / surfactants) go last — added earlier they deactivate EC / SC chemistries through premature surfactant interaction. The order is not theory; it is colloid physics.
What if the small-jar test looks fine but the tank still fails?
The small-jar test (10 mL of each in 100 mL + 15 min) catches ~85% of problems: separation, flocculation, gel, heat, gas. It does NOT catch: (a) temperature sensitivity (21°C in the jar vs 32°C in the field — abamectin and pyrethroids hydrolyze faster at higher T); (b) sunlight degradation (jar indoors, tank in the field); (c) water-source variability (municipal jar-water vs well-water at the farm — hardness, chlorine); (d) ternary kinetics (3-way interaction over 45 min of agitation — past the jar timeframe). Action: if the jar is fine but the tank fails, check the water temperature at tank-fill (target 18–25°C), the water source (well vs municipal), and consider a split application instead of a tank mix.

Sources & references

  1. 1W.A.L.E.S.+ mixing order — Purdue Extension + University of Nebraska-Lincoln + NAGRO UA pest-management guidance (canonical 6-step order)
  2. 2HRAC 2025 herbicide mode-of-action classification + IRAC v11 insecticide + FRAC 2025 fungicide (resistance-management basis)
  3. 3Law of Ukraine «Про бджільництво» №1492-III (22.02.2000, редакція 2024) — 5 km aerial / 1 km settlement / 500 m ground buffers + 48 h pre-notification
  4. 4State Register of Plant Protection Products of Ukraine (Держреєстр пестицидів) — UA-registered AI catalog, formulations, and target-crop labels
  5. 5NAAS Institute of Plant Protection (ІЗР НААН) — tank-mix compatibility research for UA crops
  6. 6ADAM UA pesticide-kb.ts Batch 3 §5 (W.A.L.E.S. + Top-30 compatibility matrix + pH windows + 4-product hard cap) + §7 (Law 1492-III bee buffers)
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